Uranium glass

Various Vaseline glassware glowing under a few UV black lights
Uranium glass used as lead-in seals in a vacuum capacitor

Uranium glass is glass which has had uranium, usually in oxide diuranate form, added to a glass mix before melting for coloration. The proportion usually varies from trace levels to about 2% by weight uranium, although some 20th-century pieces were made with up to 25% uranium.[1][2]

Uranium glass was once made into tableware and household items, but fell out of widespread use when the availability of uranium to most industries was sharply curtailed during the Cold War in the 1940s to 1990s. Most such objects are now considered antiques or retro-era collectibles, although there has been a minor revival in art glassware. Otherwise, modern uranium glass is now mainly limited to small objects like beads or marbles as scientific or decorative novelties.

Appearance

The normal colour of uranium glass ranges from yellow to green depending on the oxidation state and concentration of the metal ions, although this may be altered by the addition of other elements as glass colorants. Uranium glass also fluoresces bright green under ultraviolet light and can register above background radiation on a sufficiently sensitive Geiger counter, although most pieces of uranium glass are considered to be harmless and only negligibly radioactive.[3]

Vaseline glass

The most typical color of uranium glass is pale yellowish-green, which in the 1920s led to the nickname vaseline glass based on a perceived resemblance to the appearance of petroleum jelly as formulated and commercially sold at that time. Specialized collectors still define vaseline glass as transparent or semi-transparent uranium glass in this specific color.

Vaseline glass is now used as a synonym for any uranium glass, especially in the United States, but this usage is not universal. The term is sometimes carelessly applied to other types of glass based on certain aspects of their superficial appearance in normal light, regardless of actual uranium content which requires a blacklight test to verify the characteristic green fluorescence.

In the United Kingdom and Australia, the term vaseline glass can be used to refer to any type of translucent glass. Even within the United States, the "vaseline" description is sometimes applied to any type of translucent glass with a greasy surface luster.

Other colors

"Jadite" redirects here. It is not to be confused with Jadeite.

Several other common subtypes of uranium glass have their own nicknames:

However, like "vaseline", the terms "custard" and "jad(e)ite" are often applied on the basis of superficial appearance rather than uranium content. Similarly, Depression glass is also a general description for any piece of glassware manufactured during the Great Depression regardless of appearance or formula.

History

Pre-industrial usage

The use of uranium glass dates back to at least 79 AD,[4] the date of a mosaic containing yellow glass with 1% uranium oxide found in a Roman villa on Cape Posillipo in the Bay of Naples, Italy by R. T. Gunther of the University of Oxford in 1912.[5][6] Starting in the late Middle Ages, pitchblende was extracted from the Habsburg silver mines in Joachimsthal, Bohemia (now Jáchymov in the Czech Republic) and was used as a coloring agent in the local glassmaking industry.[5]

Martin Klaproth (1743–1817), who discovered uranium, later experimented with the use of the element as a glass colourant.

Usage

Glass fabrication

Uranium glass is used as one of several intermediate glasses in what is known to scientific glass blowers as a 'graded seal'. This is typically used in glass to metal seals such as tungsten and molybdenum or nickel based alloys such as Kovar, as an intermediary glass between the metal sealing glass and lower expansion borosilicate glass.

Modern production

Uranium glass became popular in the mid-19th century, with its period of greatest popularity being from the 1880s to the 1920s.

The first major producer of items made of uranium glass is commonly recognized as Austrian Franz Xaver Riedel, who named the yellow (German: Gelb) and yellow-green (German: Gelb-Grün) varieties of the glass "annagelb" and "annagrün", respectively, in honor of his daughter Anna Maria. Riedel was a prolific blower of uranium glass in Unter-Polaun (today Dolni Polubny), Bohemia from 1830 to 1848.

By the 1840s, many other European glassworks began to produce uranium glass items and developed new varieties of uranium glass. The Baccarat glassworks in France created an opaque green uranium glass which they named chrysoprase from its similarity to that green form of chalcedony.

At the end of the 19th century, glassmakers discovered that uranium glass with certain mineral additions could be tempered at high temperatures, inducing varying degrees of micro-crystallization. This produced a range of increasingly opaque glasses from the traditional transparent yellow or yellow-green to an opaque white. During the Depression years, more iron oxide was added to the mixture to match popular preferences for a greener glass.[7] This material, technically a glass-ceramic, acquired the name "vaseline glass" because of its supposedly similar appearance to petroleum jelly. Today, a few manufacturers continue the vaseline glass tradition: Fenton Glass, Mosser Glass, Gibson Glass and Jack Loranger.[8]

US production of uranium glasses ceased in the middle years of World War II because of the US government's confiscation of uranium supplies, and did not resume until 1958.

Riihimäki Glass produced uranium glass designer pieces after World War II.

See also

Wikimedia Commons has media related to Uranium glass.

References

  1. ↑ Big Book of Vaseline Glass, by Barrie Skelcher, Pub. Schiffer
  2. ↑ "Vaseline and uranium glass ca. 1930s"
  3. ↑ Betti, Maria (2003). "Civil use of depleted uranium" (PDF). Journal of Environmental Radioactivity. Elsevier. 64 (2-3): 113–119. doi:10.1016/S0265-931X(02)00042-5. PMID 12500798. Retrieved 2007-12-09.
  4. ↑ "Uranium". Los Alamos National Laboratory. Retrieved 2016-01-30.
  5. 1 2 Emsley, Nature's Building Blocks (2001), page 482
  6. ↑ The Earliest Known Use of a Material Containing Uranium by Earle R. Caley, Isis, Vol. 38, No. 3/4 (Feb., 1948).
  7. ↑ "Introduction". .parkcity.ne.jp. Retrieved 2014-01-05.
  8. ↑ "Vaseline Glass Collectors, Inc". Vaselineglass.org. Retrieved 2014-01-05.
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