Manganese(II) acetate

Manganese(II) acetate[1]
Names
IUPAC name
Manganese(II) acetate
Other names
Manganese diacetate
Identifiers
638-38-0 (anhydrous) YesY
6156-78-1 (tetrahydrate) N
3D model (Jmol) Interactive image
ChemSpider 12008 YesY
ECHA InfoCard 100.010.305
PubChem 12525
Properties
Mn(CH3COO)2 (anhydrous)
Mn(CH3COO)2·4H2O (tetrahydrate)
Molar mass 173.027 g/mol (anhydrous)
245.087 g/mol (tetrahydrate)
Appearance white crystals (anhydrous)
light pink monoclinic crystals (tetrahydrate)
Density 1.74 g/cm3 (anhydrous)
1.59 g/cm3 (tetrahydrate)
Melting point 210 °C (410 °F; 483 K) (anhydrous)
80 °C (tetrahydrate)
Solubility soluble in water, methanol, acetic acid (anhydrous)
soluble in water, ethanol (tetrahydrate)
Hazards
NFPA 704
Flammability code 0: Will not burn. E.g., water Health code 1: Exposure would cause irritation but only minor residual injury. E.g., turpentine Reactivity code 0: Normally stable, even under fire exposure conditions, and is not reactive with water. E.g., liquid nitrogen Special hazards (white): no codeNFPA 704 four-colored diamond
0
1
0
Flash point > 130 °C (266 °F; 403 K) (tetrahydrate)
Lethal dose or concentration (LD, LC):
2940 mg/kg (rat, oral)[2]
Related compounds
Other anions
 Manganese(II) fluoride
Manganese(II) chloride
Manganese(II) bromide
Other cations
 Zinc acetate
Mercury(II) acetate
Silver acetate
Except where otherwise noted, data are given for materials in their standard state (at 25 °C [77 °F], 100 kPa).
N verify (what is YesYN ?)
Infobox references

Manganese(II) acetate is the chemical compound with the formula Mn(CH3COO)2. It is used as a desiccant, a catalyst, and as fertilizer.[3]

Reactions

Manganese(II) acetate can be formed by reacting acetic acid with either manganese(II,III) oxide or manganese(II) carbonate:[3][4]

Mn3O4 + 2CH3COOH → Mn(CH3COO)2 + Mn2O3 + H2O

If manganese(II,III) oxide is used, manganese(III) oxide is produced as a byproduct.

If the anhydrous form needs to be produced, manganese(II) nitrate can be reacted with acetic anhydride.[3]

References

  1. ↑ Lide, David R. (1998), Handbook of Chemistry and Physics (87 ed.), Boca Raton, FL: CRC Press, pp. 3–354, 4–68, ISBN 0-8493-0594-2
  2. ↑ "Manganese compounds (as Mn)". Immediately Dangerous to Life and Health. National Institute for Occupational Safety and Health (NIOSH).
  3. 1 2 3 Thomas Scott; Mary Eagleson (1994), Concise encyclopedia chemistry, Walter de Gruyter, p. 620, ISBN 3-11-011451-8, retrieved 2009-07-20
  4. ↑ Patnaik, Pradyot (2003), Handbook of Inorganic Chemical Compounds, McGraw-Hill Professional, pp. 81–82, ISBN 0-07-049439-8, retrieved 2009-07-20
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