Gold monoiodide

Gold monoiodide
Names
IUPAC name
Iodogold
Systematic IUPAC name
Gold(1+) iodide
Other names
Gold monoiodide
Identifiers
10294-31-2
3D model (Jmol) Interactive image
ChemSpider 74478 YesY
ECHA InfoCard 100.030.584
PubChem 82526
UNII T1UDV7ES1A YesY
Properties
AuI
Molar mass 323.871 g/mol
Appearance Yellowish to greenish-yellow powder
Density 8.25 g/cm3[1]
Structure
tetragonal, Pearson symbol tP8, Z = 4
P42/ncm (No. 138)[1]
a = 0.435, b = 0.435, c = 1.373 nm
Hazards
Xi
R-phrases R36/37/38
S-phrases S26, S37/39
Except where otherwise noted, data are given for materials in their standard state (at 25 °C [77 °F], 100 kPa).
Infobox references

Gold monoiodide (AuI) is a chemical compound of gold and iodine. This compound is commercially available. It can be synthesized by heating gold and iodine in a sealed tube at 120°C for about four months. It decomposes when treated with hot water.[2] But its related complexes are much more stable.[3]

References

  1. 1 2 Jagodzinski H. (1959). "Die Kristallstruktur des AuJ". Z. Kristallogr. 112: 80–87.
  2. Greenwood, Norman N.; Earnshaw, Alan (1997). Chemistry of the Elements (2nd ed.). Butterworth-Heinemann. ISBN 0-08-037941-9.
  3. Tang, Zhongjia; Litvinchuk, A. P.; Lee, Hye-G.; Guloy, Arnold M. (1 September 1998). "Crystal Structure and Vibrational Spectra of a New Viologen Gold(I) Iodide". Inorganic Chemistry. 37 (19): 4752–4753. doi:10.1021/ic980141q.
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